Product ID:360, BERYLLIUM NICKEL ALLOYS
MSDS Date:12/01/1990
FSC:9650
NIIN:00N032652
MSDS Number: BPNFH

BRUSH WELLMAN INC

14710 W PORTAGE RIVER S ROAD
ELMORE, OH 43416-9502
US

Emergency Phone: 419-862-2745;800-424-9300(CHEMTREC)

Info Phone: 419-862-2745

Preparer: M. KOLANZ & T.N. MARKHAM

Cage: 4B151

BRUSH WELLMAN INC.

ELMORE, OH 43416-9502 US

Telephone: 800-862-4118; -4177 (FAX)

Cage: 4B151

OVERGARMENTS/WORK CLTHG SHOULD BE WORN BY

RTECS: 9999999ZZ

AS LAUNDRY OPERATORS & TO PVNT CONTAM TO

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PROPERLY LABELED AND MANAGED IN ACCORDANCE

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ALLOYS WHICH HAVE SURF SCALE/OXIDATION SHD HAVE

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OPER CONDUCTED UNDER FLOOD OF LIQ COOLANT MAY REQ

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COOLANT CONTAINING FINELY DIVIDED PARTICULATE IN

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PARTICULATE MAY BECOME AIRBORNE DURING USE. FILTER,

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VACUUM/WET CLEANING METHS ARE RECOM FOR DUST

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BEGINNING WET CLEANING. VACUUM CLEANERS W/HEPA

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DUSTS SHD BE AVOIDED. WELDING/CUTTING INDOORS,

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VENT/AIRLINE RESP UNLESS ATMOSPHERIC TESTS HAVE

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IN ALL CASES, WORKERS IN IMMED VICINITY OF OPER

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BAGS IN BAGHOUSE AIR CLEANING DEVICE.

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TO MEET ESTABLISHED OCCUP EXPOS LIMITS. WHERE

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AS CLOSE TO SOURCE OF AIRBORNE CONC AS POSS.

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MAN COOLING FAN, SHD BE AVOIDED. VENT EQUIP SHOULD

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BERYLLIUM (SARA III)

CAS: 7440-41-7

RTECS: DS1750000

Fraction By Weight: 1.8-2.3%

OSHA PEL 2 UG/M3

ACGIH TLV: 0.002PPM; A2; 9293

NICKEL (SARA III)

CAS: 7440-02-0

RTECS: QR5950000

Fraction By Weight: BALANCE

OSHA PEL 1 MG/M3

ACGIH TLV: 1 MG/M3

TITANIUM

CAS: 13463-67-7

RTECS: XR2275000

Fraction By Weight: 0.4-0.6%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST; 9293

IMPAIRMENT IF EXCESSIVE CONC OF DUST/FUME ARE

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HEMATOLOGIC/URINARY SYS HAS OCCURED, PROPER

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FLUSH W/COPIOUS AMTS OF CLEAN H*2O

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CONTACT LENSES SHOULD NOT BE WORN BECAUSE THEY MUST

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BY WET SWEEPING METHS. MIN AIRBORNE GENERATION

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LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: METAL DUST/FUMES CAN CAUSE
IRRIT TO SKIN,EYES, NOSE, THROAT, LUNGS, & MUC MEMB. SYMP MAY INCL
COUGH, METALLIC TASTE IN MOUTH, FEVER, FATIGUE,& NAUS. EXCESSIVE
INHAL OF COPPER/NICKEL CAN CAUSE R ESP IRRIT, COUGH, BRONCH,
CHILLS, "METAL FUME FEVER", DECREASED PULM FUNCT & ASTHMA-LIKE
SYMP. CONT W/ (EFTS OF OVEREXP)
Explanation of Carcinogenicity:BERYLLIUM: GROUP 2A (IARC), ANTICIPATED
TO BE CARCIN (NTP). NICKEL: GROUP 2B (IARC), ANTICIPATED TO BE
CARCINOGEN (NTP)
Effects of Overexposure:HLTH HAZ: COBALT,COPPER, NICKEL MAY CAUSE
ALLERGIC SKIN RXNS. CHRONIC: METAL DUST/FUMES CAN CAUSE RESP
DISEASE W/SYMP WHICH INCL COUGH, CHEST PAIN, SHORTNESS OF BRTH, WT
LOSS, WEAK & FATIGUE. EXCESSIV E EXPOS TO AIRBORNE PARTICULATE
CONTAINING BERYLLIUM, COBALT/NICKEL MAY CAUSE LONG-TERM HLTH EFTS
INCL LOSS OF (SUPDAT)
Medical Cond Aggravated by Exposure:INDIV WHO MAY HAVE HAD ALLERGIC RXN
TO CO, CU MAY ENCOUNTER SKIN RASH/DERM. PERSONS W/IMPAIRED PULM
FUNCT, AIRWAY DISEASES/CNDTNS SUCH AS ASTHMA, EMPHYSEMA, CHRONIC
BRONCH, ETC. MAY INCUR (SUPDAT)

First Aid:INHAL:IMMED REMOVE TO FRESH AIR.IF BRTHG HAS STOPPED, PERFORM
ARTF RESP & OBTAIN MED HELP.INGEST: HAVE AFFECTED PERSON DRINK LRG
QTYS OF H2O & ATTEMPT TO INDUCE VOMIT IF CONSCIOUS. OBTAIN MED
HELP.SKI N: CUTS/ABRASIONS CAN BE TREATED BY STDFIRST AID. CONTAM
CAN BE REMOVED BY WASHING W/SOAP & H2O.IF IRRIT PERSISTS OBTAIN MED
HELP. ACCIDENTAL IMPLANTATION OF MATL BENEATH SKIN REQS REMOVAL.
(ING 6)

Flash Point:NON-COMBUSTIBLE
Extinguishing Media:ALLOYS ARE NON-COMBUSTIBLE. USE EXTINGUISHING MEDIA
APPROPRIATE TO SURROUNDING FIRE.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:DO NOT USE WATER TO EXTINGUISH FIRES
AROUND OPERATIONS INVOLVING MOLTEN METAL DUE TO POTENTIAL FOR STEAM
EXPLOSIONS.

Spill Release Procedures:IF MATL IS IN POWDER/DUST FORM, ESTABLISH
RESTRICTED ENTRY ZONE. PERSONS ENTERING RESTRICTED ZONE MUST WEAR
ADEQ RESP PROT/PROT CLTHG. CLEANUP SHOULD BE CONDUCTED W/VACUUM SYS
UTILIZING HIGH EFFICIENC Y PARTICULATE AIR FILTRATION SYS FOLLOWED
(ING 8)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER.
Other Precautions:AIRBORNE EXPOS CAN OCCUR WHEN MELTING, CASTING, DROSS
HNDLG, PICKLING, WELDING, GRINDING, SANDING, POLISHING, MILLING,
CRUSHING/ OTHERWISE ABRADING SURF OF ALLOYS IN MANNER WHICH
GENERATES FINELY DIVI DED PARTICLES. CAST/HEAT TREATED (ING 10

Respiratory Protection:WHEN EXPOS LIMITS EXCEEDED,NIOSH/MSHA APPRVD
RESP MUST BE USED. EXPOS TO UNKNOWN CONC OF FUMES/DUSTS REQS
PRESS-DEMAND AIRLINE RESP/PRESS-DEMAND SCBA. PRESS-DEMAND AIRLINE
RESP ARE RECOM FOR JOBS W/HI GH POTNTL EXPOS SUCH AS CHANGING(ING
19)
Ventilation:WHENEVER POSS USE OF LOC EXHST VENT/OTHER ENGINEERING
CNTRLS IS PREF METH OF CNTRLG EXPOS TO AIRBORNE DUST/FUME (ING 20)
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:CHEM WORK GOG/FULL LGTH FACESHLD .
Other Protective Equipment:PROT CLTHG SUCH AS FIRE RETARDANT CLTHG, &
MOLTEN METAL SPLASH RESISTANT GARMENTS SHOULD BE WORN AS NEC. PROT
(ING 23)
Work Hygienic Practices:WASH HANDS BEFORE EATING/SMOKING. CONTAM WORK
CLTHG & OVERGARMENTS SHD BE MANAGED TO PVNT EXPOS TO PERSONS SUCH
(ING 24)
Supplemental Safety and Health
EFTS OF OVEREXP:LUNG FUNCT, FIBROSIS/ SUBSEQUENT SECONDARY EFTS OF
HEART W/EVENTUAL PERM IMPAIRMENT. OVEREXP TO AIRBORNE BERYLLIUM
PARTICULATE MAY CAUSE CHRONIC BERYLLIUM DISEASE, A CNDTN IN WHICH
TIS S OF LUNGS BECOME INFLAMED, RESTRICTINGEXCHANGE OF OXYGEN
BETWEEN LUNGS AND BLOODSTREAM. MED CNDTNS: FURTHER (ING 4)

HCC:N1
Melt/Freeze Pt:M.P/F.P Text:2100F,1149C
Vapor Density:0.296
Solubility in Water:NONE
Appearance and Odor:SOLID GREYISH SILVER, NO ODOR.
Percent Volatiles by Volume:NONE

Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH MINERAL ACIDS AND OXIDIZING AGENTS WHICH MAY
GENERATE HYDROGEN GAS. HYDROGEN GAS CAN BE EXPLO HAZ.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:NONE UNDER NORMAL CONDITIONS OF USE.

Waste Disposal Methods:WHEN SPENT, ALLOYS ARE NOT CLASSIFIED AS HAZ
WASTES UNDER FED LAW & ARE NORMALLY RECYCLED. DUST-LIKE MATLS SUCH
AS BAGHOUSE FINES SHOULD BE SEALED IN PLASTIC BAG & THEN PLACED IN
SOUND CNTNR & APPROP IDENTIFIED. ALL WASTE MATLS SHOULD BE (ING 9)

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This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.